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生物脱硫中在含尘量500mg/m³的焦炉煤气工况下,如何保证生物滤床不板结?

  在含尘量为 500mg/m³ 的焦炉煤气工况下,生物滤床容易因粉尘堆积导致板结,影响滤床透气性和处理效率。以下是从预处理、滤床设计、运行管理及维护等方面提出的针对性解决方案:

  Under the condition of coke oven gas with a dust content of 500mg/m ³, the biofilter bed is prone to compaction due to dust accumulation, which affects the permeability and treatment efficiency of the filter bed. The following are targeted solutions proposed from the aspects of preprocessing, filter bed design, operation management, and maintenance:

  一、强化预处理,减少粉尘负荷

  1、 Strengthen pre-processing to reduce dust load

  焦炉煤气中的粉尘(如焦油、煤灰、硫化物颗粒等)是导致滤床板结的主要原因,需在气体进入生物滤床前进行有效拦截。

  The dust (such as tar, coal ash, sulfide particles, etc.) in coke oven gas is the main cause of bed compaction, and effective interception is required before the gas enters the biological filter bed.

  多级除尘工艺

  Multi stage dust removal process

  旋风除尘:利用离心力去除较大颗粒粉尘(>10μm),降低后续负荷。

  Cyclone dust removal: using centrifugal force to remove larger particles of dust (>10 μ m) and reduce subsequent loads.

  湿式洗涤 / 喷淋塔:通过水雾捕集细小粉尘(1-10μm),同时吸收部分水溶性污染物(如 HS),并调节气体湿度(避免滤床干燥开裂)。

  Wet scrubbing/spraying tower: captures fine dust (1-10 μ m) through water mist, while absorbing some water-soluble pollutants (such as H  S) and adjusting gas humidity (to avoid drying and cracking of the filter bed).

  过滤装置:采用布袋除尘器或滤芯式过滤器(精度≥1μm),进一步截留微细粉尘,确保进入滤床的气体含尘量<50mg/m³(理想值<20mg/m³)。

  Filtering device: Adopting bag filter or filter cartridge type filter (accuracy ≥ 1 μ m) to further intercept fine dust and ensure that the dust content of the gas entering the filter bed is less than 50mg/m ³ (ideal value<20mg/m³).

  焦油预处理:焦炉煤气中常含焦油雾,易黏附滤料,需通过电捕焦油器或冷凝法去除,避免焦油与粉尘形成黏性团块。

  Tar pretreatment: Coke oven gas often contains tar mist, which can easily adhere to filter media. It needs to be removed by an electric tar catcher or condensation method to avoid the formation of viscous lumps between tar and dust.

  二、优化生物滤床设计,提升抗板结能力

  2、 Optimize the design of the biological filter bed to enhance its anti caking ability

  滤料选择与级配

  Filter material selection and grading

  材质:选用孔隙率高(>40%)、比表面积大(100-300m²/m³)、机械强度高的滤料,如火山岩、陶粒、聚氨酯泡沫、改性塑料颗粒等。避免使用易被粉尘堵塞的木质填料或细颗粒填料。

  Material: filter material with high porosity (>40%), large specific surface area (100-300m²/m³) and high mechanical strength, such as volcanic rock, ceramsite, polyurethane foam, modified plastic particles, etc. Avoid using wooden or fine particle fillers that are easily clogged by dust.

  粒径分级:采用多层级配滤料(如底层粗颗粒 30-50mm,中层中颗粒 15-30mm,上层细颗粒 5-15mm),形成 “上疏下密” 结构,延长粉尘穿透路径,减少表层堆积。

  Particle size grading: Multiple layers of graded filter media are used (such as 30-50mm coarse particles in the bottom layer, 15-30mm medium particles in the middle layer, and 5-15mm fine particles in the upper layer) to form a "sparse top and dense bottom" structure, extending the path of dust penetration and reducing surface accumulation.

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  亲生物性处理:对滤料表面进行改性(如涂层、挂膜预处理),促进微生物附着,减少粉尘直接黏附。

  Biophilic treatment: Modify the surface of the filter material (such as coating, membrane pretreatment) to promote microbial adhesion and reduce direct dust adhesion.

  布气与排水系统

  Gas distribution and drainage system

  均匀布气:采用穿孔管布气或气体分布板,确保气流均匀通过滤床,避免局部流速过高加剧粉尘冲刷或过低导致粉尘沉积。

  Uniform gas distribution: Perforated pipes or gas distribution plates are used to ensure that the airflow passes evenly through the filter bed, avoiding excessive local flow velocity that exacerbates dust erosion or low flow velocity that leads to dust deposition.

  反冲洗 / 曝气设计:

  Backwash/aeration design:

  在滤床底部设置反冲洗管道,定期用清水或低压空气(50-100kPa)反向冲刷滤料,剥离粉尘和老化生物膜。

  Install a backwash pipeline at the bottom of the filter bed, regularly backwash the filter material with clean water or low-pressure air (50-100kPa) to remove dust and aged biofilm.

  对于需供氧的好氧生物滤床,可通过间歇曝气(如每 12 小时曝气 30 分钟)实现 “气洗”,同时抑制厌氧发酵产生的黏性物质。

  For aerobic biofilters that require oxygen supply, intermittent aeration (such as 30 minutes of aeration every 12 hours) can be used to achieve "air washing" while suppressing the viscous substances produced by anaerobic fermentation.

  排水坡度:滤床底部设置≥5% 的坡度,配合集水沟,确保反冲洗废水和冷凝水快速排出,避免积水浸泡滤料导致板结。

  Drainage slope: A slope of ≥ 5% is set at the bottom of the filter bed, equipped with a collection ditch to ensure the rapid discharge of backwash wastewater and condensate water, and to avoid water accumulation soaking the filter material and causing compaction.

  滤床结构优化

  Optimization of filter bed structure

  分层设置:将滤床分为预处理层(上层,填充活性炭或惰性填料吸附粉尘)和生物反应层(下层,填充微生物载体),定期更换预处理层填料以减少粉尘渗入生物层。

  Layered setting: Divide the filter bed into a pre-treatment layer (upper layer, filled with activated carbon or inert fillers to adsorb dust) and a biological reaction layer (lower layer, filled with microbial carriers), and regularly replace the pre-treatment layer fillers to reduce dust infiltration into the biological layer.

  扩容设计:适当增加滤床高度(如 3-5m)和横截面积,降低表面负荷(建议空床停留时间>60 秒),减少单位面积粉尘沉积量。

  Expansion design: Appropriately increase the height (such as 3-5m) and cross-sectional area of the filter bed, reduce surface load (recommended empty bed residence time>60 seconds), and reduce the amount of dust deposition per unit area.

  三、精细化运行管理,控制关键参数

  3、 Refined operation management, control key parameters

  湿度与温度调控

  Humidity and temperature regulation

  气体湿度维持在 80%-95%,避免滤料干燥导致粉尘附着力增强;若气体温度过高(如>60℃),需先通过换热器降温至 25-40℃(微生物最佳活性温度),同时减少高温对滤料结构的破坏。

  Maintain gas humidity at 80% -95% to avoid dust adhesion enhancement caused by filter material drying; If the gas temperature is too high (such as>60 ℃), it needs to be cooled to 25-40 ℃ (the optimal temperature for microbial activity) through a heat exchanger, while reducing the damage of high temperature to the filter material structure.

  微生物活性维持

  Microbial activity maintenance

  定期监测滤床 pH 值(中性或微碱性为宜)、营养盐(N、P 等)含量,通过喷淋系统补充缺失的养分(如尿素、磷酸盐),避免微生物因代谢产物积累或营养不足导致活性下降、生物膜过度增厚。

  Regularly monitor the pH value (neutral or slightly alkaline) and nutrient content (N, P, etc.) of the filter bed, and supplement missing nutrients (such as urea, phosphate) through a spray system to avoid microbial activity decline and excessive biofilm thickening caused by metabolic product accumulation or nutrient deficiency.

  优选耐粉尘、抗冲击的微生物菌种(如芽孢杆菌、假单胞菌),可通过固定化技术提高菌群附着稳定性,减少随反冲洗流失。

  Selecting microbial strains that are resistant to dust and impact (such as Bacillus and Pseudomonas) can improve the stability of bacterial attachment through immobilization technology and reduce loss during backwashing.

  粉尘负荷监控

  Dust load monitoring

  在线监测进气和出气含尘量,当压差(反映滤床阻力)超过 500Pa 时,触发反冲洗程序;若频繁反冲洗仍无法降低阻力,需检查预处理系统是否失效。

  Online monitoring of intake and exhaust dust content, triggering backwash program when pressure difference (reflecting filter bed resistance) exceeds 500Pa; If frequent backwashing still fails to reduce resistance, it is necessary to check whether the pre-treatment system has failed.

  本文由生物脱硫友情奉献.更多有关的知识请点击:https://www.hneee.net我们将会对您提出的疑问进行详细的解答,欢迎您登录网站留言.

  This article is a friendly contribution from biogas purification For more information, please click: https://www.hneee.net We will provide detailed answers to your questions. You are welcome to log in to our website and leave a message

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